Sunday, June 1, 2008

Bixbite red beryl rough gemstone

Bixbite (also known as red beryl, red emerald, or scarlet emerald) is a red variety of beryl (emerald), Be3(Al,Mn)2Si6O18. It was named after the Utah mineral collector Maynard Bixby. Other local or discredited names include sitaparite and partridgeite. Bixbite is rare and has only been reported from a handful of locations including:

Wah Wah mountains, Juab County, Utah Paramount Canyon, Sierra County, New Mexico Round Mountain, Sierra County, New Mexico Thomas Range, Beaver County, Utah The greatest concentration of gem-grade red beryl comes from the Violet Claim in the Wah Wah mountains of mid-western Utah.

Bixbite occurs in topaz-bearing rhyolites. It formed by crystallizing under low pressure and high temperature from a pneumatolitic phase along fractures or within miarolitic cavities and rhyolitic magmas near the surface. Minerals it is found with include bixbyite, quartz, orthoclase, topaz, spessartine garnet, pseudobrookite and hematite. The red color is thought to be from manganese substituting for aluminium in the beryl structure.

Gem-quality bixbite is very rare, and the largest faceted gemstones are less than three carats (600 mg) in size.








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Heliodor yellow beryl rough gemstones


The mineral beryl is a beryllium aluminium cyclosilicate with the chemical formula Be3Al2(SiO3)6. The hexagonal crystals of beryl may be very small or range to several meters in size. Terminated crystals are relatively rare. Beryl exhibits conchoidal fracture, has a hardness of 7.5–8, a specific gravity of 2.63–2.80. It has a vitreous luster and can be transparent or translucent. Its cleavage is poor basal and its habit is dihexagonal bipyramidal. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, red, and white. The name comes from the Greek beryllos for the precious blue-green color of sea water.



Varieties Varieties of beryl have been considered gemstones since prehistoric times. Recognized for its beauty, in the Bible, in Ezekiel 1:16, the wheels of God's throne are described as having the appearance of "gleaming beryl". Green beryl is called emerald, red beryl is bixbite or red emerald or scarlet emerald, blue beryl is aquamarine, pink beryl is morganite, white beryl is goshenite, and a clear bright yellow beryl is called golden beryl. Other shades such as yellow-green for heliodor and honey yellow are common. Red beryl is extremely rare and is not used in jewelry as the crystals it forms are very small. Blue beryl (aquamarine) when exposed to sunlight will not fade in color. Maxixe type beryl is a deep blue stone that fades to white when exposed to sunlight or is subjected to heat treatment, color returns with irradiation

Deposits Beryl is found most commonly in granitic pegmatites, but also occurs in mica schists in the Ural Mountains and is often associated with tin and tungsten orebodies. Beryl is found in certain European countries such as Austria, Germany, and Ireland. It also occurs in Madagascar (especially morganite).

The most famous source of emeralds in the world is at Muzo and Chivor, Boyacá, Colombia, where they make a unique appearance in limestone. Emeralds are also found in the Transvaal, South Africa, Minas Gerais, Brazil, and near Mursinka in Urals. In the United States emeralds are found in North Carolina. New England's pegmatites have produced some of the largest beryls found, including one massive crystal with dimensions 5.5 m by 1.2 m (18 ft by 4 ft) with a mass of around 18 metric tons. It is New Hampshire's State Mineral. Other beryl locations include South Dakota, Colorado, Utah, Idaho, and California.

As of 1999, the largest known crystal of any mineral in the world is a crystal of beryl from Madagascar, 18 metres long and 3.5 metres in diameter.









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Morganite rough pink beryl gemstone


Morganite is a pink colored gem quality beryl, orange/yellow morganite is sometimes also found, it turns pink upon high temperature treatment. Color banding is common in morganite.

J. P. Morgan By the turn of the century, J. P. Morgan (the famous financier) had become one of the most important collectors of gems and minerals and had assembled the most important gem collection in the USA as well as of American gemstones (over 1,000 pieces). Tiffany & Co. actually assembled his first collection -- which basically implied that their "chief gemologist" George Frederick Kunz built the collection for J.P. Morgan -- which was exhibited at the World's Fair in Paris in 1889. The exhibit won two golden awards and drew the attention of important scholars, lapidaries, and the general public.

George Frederick Kunz then continued to build a second, even finer, collection, which was exhibited in Paris in 1900. Collections were donated to the American Museum of Natural History in New York, where they were known as the Morgan-Tiffany and the Morgan-Bement collections.

One of the larger Morganites retrieved from the Elizabeth Mine in Pala, California, in 2005. Specimen shows attached matrix of Muscovite and Albite. Photo Courtesy John Veevaert, Trinity Minerals [edit] The discovery Morganite was first discovered together with other gemstone minerals, such as Tourmaline and Kunzite, in California in the early twentieth century at Pala. This started a bonanza for these quite popular gemstones which drew the attention of George Frederick Kunz, knowing Pink Beryl was quite a rarity.

It was George Frederick Kunz who, in 1911, suggested to name the pink variety of Beryl Morganite, after his biggest customer - J.P. Morgan. [4]. Ever since, the stone has held a certain popularity with Tiffany's though it still remains a relatively scarce gem.

[edit] Chemical and physical properties The chemical formula of morganite is: Be3Al2(SiO3)6 beryllium-aluminium silicate.

The chemical composition of beryl is beryllium (14%) aluminium (19%) silicate (67%), usually containing alkali ions, other minerals, water, and gases. It crystallizes in hexagonal shapes, known as habit, and is in the dihexagonal-dipyramidal class of the Hexagonal crystal system. Beryls sometimes crystalize in well formed hexagonal prisms with pedion (flat) terminations. It has refractive index values of 1.57 to 1.58 with weak dichroism. Cleavage is absent to poor in one direction. The hardness is 7.5-8 on the Mohs hardness scale, and the specific gravity ranges from 2.66-2.83.

Many sources attribute morganite's color to the element manganese in interstitial sites in the beryl's ring structure. Other references attribute the color to the element cesium.

[edit] Different types of Beryl Colorless - goshenite, Green - emerald, Blue & blue/green - aquamarine, Pink - morganite, Yellow - heliodor, Red - bixbite

Morganite may also be known as pink beryl, or in the jewelry trade as pink emerald. Attempts to change the names of beryl gem varieties are a matter of some contention in the gem trade.

[edit] Value as a gemstone Morganite is generally considered to be about as common as the other beryls, aquamarine and heliodor. Its value is influenced by demand, and is generally less well known than aquamarine, tending to depress its value. The only beryl which is considered to be rare, other than emerald, is the Red Beryl, bixbite which is primarily found in the Wah-Wah Mountains of Utah.

Enhancements Morganite should be considered to be routinely heat treated to remove patches of yellow.









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Emerald rough gemstones



Emerald with host rock General Category Mineral Chemical formula Beryllium aluminium silicate with chromium, Be3Al2(SiO3)6::Cr Identification Color Green Crystal habit Hexagonal Crystals Crystal system Hexagonal Cleavage Poor Basal Cleavage (Seldom Visible) Fracture Conchoidal Mohs Scale hardness 7.5 - 8.0 Luster Vitreous Refractive index 1.576 - 1.582 Pleochroism Distinct, Blue-Green/Yellow-Green Streak White Specific gravity 2.70 - 2.78 Emerald (Be3Al2(SiO3)6) is a variety of the mineral beryl, colored green by trace amounts of chromium and sometimes vanadium. It is highly prized as a gemstone and by weight is the most valuable gemstone in the world, although it is often made less so by inclusions, which all emeralds have to some degree. Beryl has a hardness of 7.5 - 8 on the 10 point Mohs scale of hardness.[2] However, the effective hardness of an emerald is often reduced by fractures and inclusions. Most emeralds are highly included, so the toughness (resistance to breakage) is classified as generally poor.

Emeralds come in many shades of green and bluish green. There is a wide spectrum of clarity, dependent on the inclusions and fractures in the crystal. Clear stones with dark yet vibrant color command the highest prices.

Most emeralds are oiled as part of the post lapidary process, in order to improve their clarity. Cedar oil is often used, having a similar refractive index, and it is a generally accepted practice. The U.S. Federal Trade Commission requires the disclosure of this type of treatment when a treated emerald is sold.[3] The amount of oil entering an emerald microfissure is roughly equivalent to the size of a period (full stop) in print[citation needed]. The use of green tinted oil is generally not considered acceptable by the gem trade.

Emeralds in antiquity were mined by the Egyptians and in Austria, as well as Swat in northern Pakistan.

A rare type of emerald known as a trapiche emerald is occasionally found in the mines of Colombia. A trapiche emerald exhibits a "star" pattern; it has raylike spokes of dark carbon impurities that give the emerald a six-pointed radial pattern. It is named for the trapiche, a grinding wheel used to process sugarcane in the region. Colombian emeralds are generally the most prized due to their transparency and fire. Some of the most rare emeralds come from three main emerald mining areas in Colombia: Muzo, Coscuez, and Chivor. Fine emeralds are also found in other countries, such as Zambia, Brazil, Zimbabwe, Madagascar, Pakistan, India, Afghanistan and Russia.

The value of an emerald depends on cut, color, clarity, and carat. The characteristics of Colombian emeralds set the highest standards of quality.

Synthetic emerald

Emerald showing its hexagonal structureEmerald is a rare and valuable gemstone and, as such, it has provided the incentive for developing synthetic emeralds. Both hydrothermal and flux-growth synthetics have been produced, and a method has been developed for producing an emerald overgrowth on colourless beryl. The first commercially successful emerald synthesis process was that of Carroll Chatham. Because Chatham's emeralds do not have any water and contain traces of vanadate, molybdenum and vanadium, a lithium vanadate flux process is probably involved. The other large producer of flux emeralds is Pierre Gilson Sr., which has been on the market since 1964. Gilson's emeralds are usually grown on natural colourless beryl seeds which become coated on both sides. Growth occurs at the rate of 1 mm per month and a typical seven-month growth run produces emerald crystals of 7 mm of thickness (Nassau, K. Gems Made By Man, 1980).

Hydrothermal synthetic emeralds have been attributed to IG-Farben, Nacken, Tairus and others, but the first satisfactory commercial product was that of Johann Lechleitner of Inbruck, Austria, which appeared on the market in the 1960s. These stones were initially sold under the names "Emerita" and "Symeralds", and they were grown as a thin layer of emerald on top of natural colourless beryl stones. Although not much is known about the original process, it is assumed that Leichleitner emeralds were grown on acid conditions. Later, from 1965 to 1970, the Linde Division of Union Carbide produced completely synthetic emeralds by hydrothermal synthesis. According to their patents (US3,567,642 and US3,567,643), acidic conditions are essential to prevent the chromium (which is used as the colourant) from precipitating. Also, it is important that the silicon containing nutrient be kept away from the other ingredients in order to prevent nucleation and confine growth to the seed crystals. Growth occurs by a diffusion-reaction process, assisted by convection. Typical growth conditions include pressures of 700-1400 bars at temperatures of 500 to 600°C with a temperature gradient of 10 to 25°C. Growth rates as fast as 1/3 mm per day can be attained

Luminescence in ultraviolet light is considered a supplementary test when making a natural vs. synthetic determination, as many, but not all, natural emeralds are inert to ultraviolet light. Many synthetics are also UV inert.

Synthetic emeralds are often referred to as "created", as their chemical and gemological composition is the same as their natural counterparts. The U.S. Federal Trade Commission (FTC) has very strict regulations as to what can and what cannot be called "synthetic" stone. The FTC says: "§ 23.23(c) It is unfair or deceptive to use the word "laboratory-grown," "laboratory-created," "[manufacturer name]-created," or "synthetic" with the name of any natural stone to describe any industry product unless such industry product has essentially the same optical, physical, and chemical properties as the stone named."

Wispy veil-like inclusions are common in flux-grown synthetic emeralds.

Cultural and historical/mythical usage

The Gachala Emerald is one of the largest gem emeralds in the world at 858 carats. This stone was found in 1967 at La Vega de San Juan mine in Gachalá, Colombia. It is housed at the National Museum of Natural History of the Smithsonian Institution in Washington DC.Emerald is regarded as the traditional birthstone for May, as well as the traditional gemstone for the astrological signs of Taurus and Cancer.

According to Rebbenu Bachya, and the King James Version, the Hebrew word Nofech in Exodus 28:18 means Emerald, and was the stone on the Hoshen representing the tribe of Judah. However, the Septuagint translates the word as Anthrax, meaning coal, probably in reference to the colour of burning coal, and therefore many rabbinical sources, and most scholars, consider Nofech to mean a red garnet – traditionally called a carbuncle (gemstone), which happens to be the Vulgate's translation of the word. There is a wide range of views among traditional sources about which tribe the stone refers to.

Another candidate among the stones of the Hoshen for an Emerald is the stone referred to as a bareqet. Although bareqet means shiny, the Septuagint translates the word as Smaragdos, which is the Greek word that Emerald derives from. But Smaragdos is a false friend, as it actually just means green stone, and was used to refer to bright and translucent columnar green crystals – Heliodor, which is lighter than Emerald, is more likely to be the meaning. There is a wide range of views among traditional sources about which tribe this stone refers to as well.

The third candidate in the Hoshen for being an Emerald is the stone referred to as a Yasepheh. The New International Version translates the term as Emerald. The term actually means Jasper, and is cognate with the word; although Jasper is usually red, green Jasper was rarer and more valuable and the term Jasper was used in the classical era to refer to green Jasper. Jasper is very opaque, and quite dissimilar to Emeralds. For various reasons, some Targums translate the term Yasepheh as yellow zircon, red ruby, or Emeralds.

In some cultures, the emerald is the traditional gift for the 55th wedding anniversary. It is also used as a 20th and 35th wedding anniversary stone.

Famous emeralds Gachala Emerald (origin: Colombia) Chalk Emerald (origin: Colombia) Nidvin Emerald (origin: Colombia) Duke of Devonshire Emerald (origin: Colombia) Mackay Emerald Greenshorkire Emerald Edward the Confessor Emerald in the Imperial State Crown of Great Britain









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Aquamarine rough gemstones


General Category beryl mineral variety Chemical formula Be3Al2Si6O18 Identification Color transparent (or can be translucent if included), greenish blue to blue green, typically light in tone Crystal system hexagonal Cleavage very difficult in one direction, almost never seen Fracture conchoidal Mohs Scale hardness 7.5 - 8 Luster vitreous to resinous Polish luster vitreous Refractive index 1.577 - 1.583 (+/- .017) Optical Properties Double refractive, uniaxial negative Birefringence .005 - .009 Dispersion .014 Pleochroism weak to moderate, blue and greenish blue; or different tones of blue with lighter tones associated with the optic axis direction Ultraviolet fluorescence inert Absorption spectra indistinct lines at 537 and 456nm. Depending on the depth of color, there is a strong line at 427nm. Specific gravity 2.72 (+.18, -.05) Aquamarine (Lat. aqua marin¨¡, "water of the sea") is a gemstone-quality transparent variety of beryl, having a delicate blue or turquoise color, suggestive of the tint of seawater. It's closely related to the gem emerald. Colors vary and yellow beryl, called heliodor; rose pink beryl, morganite; and white beryl, goshenite are known.

Aquamarine is a beryl with a hexagonal crystal structure and a chemical formula of Be3Al2Si6O18, a beryllium aluminium silicate mineral. It has a specific gravity of 2.68 to 2.74 and a Mohs hardness of from 7.5 to 8. Aquamarine typically is on the low end of the specific gravity range, normally at less than 2.7. The pink variety exhibits a high specific gravity of around 2.8. Refractive indices range around 1.57 to 1.58.

It occurs at most localities which yield ordinary beryl, some of the finest coming from Russia. The gem-gravel placer deposits of Sri Lanka contain aquamarine. Clear yellow beryl, such as occurs in Brazil, is sometimes called aquamarine chrysolite. When corundum presents the bluish tint of typical aquamarine, it is often termed Oriental aquamarine.

In the United States, aquamarines can be found at the summit of Mt. Antero in the Sawatch Range in central Colorado. In Brazil, there are mines in the states of Minas Gerais, Esparito Santo and Bahia. Zambia also produces nice aquamarine as well as Madagascar, Malawi, Tanzania and Kenya. Much of today's aquamarine is heated to give it a better color blue. The deeper the blue color, the more valuable the gem is considered.

The biggest aquamarine ever mined was found at the city of Marambaia, Minas Gerais, Brazil, in 1910. It weighed over 110 kg, and its dimensions were 48.5 cm long and 42 cm in diameter.

Aquamarine is the official state gem of Colorado.

Culture and historical/mythical usage Aquamarine (along with Bloodstone) is the birthstone associated with March. It is also the gemstone for the 19th Anniversary. People in the Middle Ages thought that aquamarine could magically overcome the effects of poison. Ancient sailors traveled with aquamarine crystals, believing that it would ensure a safe passage, and often slept with the stones under their pillow to ensure sound sleep. They believed the siren¡¯s (mermaid) fish-like lower body was made of aquamarine.








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Saturday, May 31, 2008

Beryl rough gemstones



BERYL
Three varieties of beryl: Morganite, Aquamarine, and HeliodorThe mineral beryl is a beryllium aluminium cyclosilicate with the chemical formula Be3Al2(SiO3)6. The hexagonal crystals of beryl may be very small or range to several meters in size. Terminated crystals are relatively rare. Beryl exhibits conchoidal fracture, has a hardness of 7.5–8, a specific gravity of 2.63–2.80. It has a vitreous luster and can be transparent or translucent. Its cleavage is poor basal and its habit is dihexagonal bipyramidal. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, red, and white. The name comes from the Greek beryllos for the precious blue-green color of sea water.

Varieties Varieties of beryl have been considered gemstones since prehistoric times. Recognized for its beauty, in the Bible, in Ezekiel 1:16, the wheels of God's throne are described as having the appearance of "gleaming beryl". Green beryl is called emerald, red beryl is bixbite or red emerald or scarlet emerald, blue beryl is aquamarine, pink beryl is morganite, white beryl is goshenite, and a clear bright yellow beryl is called golden beryl. Other shades such as yellow-green for heliodor and honey yellow are common. Red beryl is extremely rare and is not used in jewelry as the crystals it forms are very small. Blue beryl (aquamarine) when exposed to sunlight will not fade in color. Maxixe type beryl is a deep blue stone that fades to white when exposed to sunlight or is subjected to heat treatment, color returns with irradiation

Deposits Beryl is found most commonly in granitic pegmatites, but also occurs in mica schists in the Ural Mountains and is often associated with tin and tungsten orebodies. Beryl is found in certain European countries such as Austria, Germany, and Ireland. It also occurs in Madagascar (especially morganite).

The most famous source of emeralds in the world is at Muzo and Chivor, Boyacá, Colombia, where they make a unique appearance in limestone. Emeralds are also found in the Transvaal, South Africa, Minas Gerais, Brazil, and near Mursinka in Urals. In the United States emeralds are found in North Carolina. New England's pegmatites have produced some of the largest beryls found, including one massive crystal with dimensions 5.5 m by 1.2 m (18 ft by 4 ft) with a mass of around 18 metric tons. It is New Hampshire's State Mineral. Other beryl locations include South Dakota, Colorado, Utah, Idaho, and California.

As of 1999, the largest known crystal of any mineral in the world is a crystal of beryl from Madagascar, 18 metres long and 3.5 metres in diameter.

Applications Massive beryl is a primary ore of the metal beryllium.









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Spinel Gemstones from Tanzania




The spinels are any of a class of minerals which crystallize in the isometric system with an octahedral habit. The general formula is as (X)(Y)2O4, with X representing cations occupying tetrahedral sites and Y cations occupying octahedral sites. Divalent, trivalent, and quadrivalent cations can occupy the X and Y sites, and they include magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon.

The oxygen anions are arranged in a cubic close-packed structure. In the normal spinel structure, X cations occupy the tetrahedral sites, and Y the octahedral sites. For inverse spinels, half the Y cations occupy the tetrahedral sites, and both X and Y cations occupy the octahedral sites.

Important members of the spinel group include:

Spinel – MgAl2O4, after which this class of minerals is named Gahnite - ZnAl2O4 Franklinite - (Fe,Mn,Zn)(Fe,Mn)2O4 Chromite - (Fe·Mg)Cr2O4 Magnetite - Fe3O4 Hercynite - FeAl2O4 Ulvöspinel - TiFe2O4 Jacobsite - MnFe2O4 Trevorite - NiFe2O4 Ringwoodite - SiMg2O4, an abundant olivine polymorph within the Earth's mantle from about 520 to 660 km depth, and a rare mineral in meteorites True spinel has long been found in the gemstone-bearing gravel of Sri Lanka and in limestones of Myanmar and Thailand.

Spinel usually occurs in isometric crystals, octahedrons, usually twinned. It has an imperfect octahedral cleavage and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5-4.1 and it is transparent to opaque with a vitreous to dull lustre. It may be colorless, but is usually various shades of red, blue, green, yellow, brown or black. There is a unique natural white spinel, now lost, that surfaced briefly in what is now Sri Lanka. Another famous spinel is the Black Prince's Ruby in the British Crown Jewels.

The transparent red spinels are called spinel-rubies or balas-rubies and were often confused with actual rubies in ancient times. "Balas" is derived from Balascia, the ancient name for Badakhshan, a region in central Asia situated in the upper valley of the Kokcha river, one of the principal tributaries of the Oxus river. Yellow spinel is called rubicelle and violet-colored manganese-bearing spinel is called almandine.

Spinel is found as a metamorphic mineral, and also as a primary mineral in basic rocks, because in such magmas the absence of alkalis prevents the formation of feldspars and any aluminium oxide present will form corundum or combine with magnesia to form spinel. This is why spinel and ruby are often found together.

Spinel, (Mg,Fe)(Al,Cr)2O4, is common in peridotite in the uppermost Earth's mantle, between the Mohorovicic discontinuity (the Moho) and a depth of 70 kilometers or so; below that depth, the spinel (if present) becomes increasingly rich in chromium, as with increasing depth, pyrope-rich garnet becomes the more stable aluminous mineral in peridotite. At depths significantly shallower than the Moho, calcic plagioclase is the more stable aluminous mineral in peridotite.




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